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  •  Cornflour   
    25/09/03 @ 15:00 BSTDave  
    Chemistry Exps

    This is a selection of strange fluids, and particle effects grouped together, mainly just because they are fascinating to play with. A warning: you will get covered in Cornflour!



    Kit list:

    1. Washing up bowls 3-4
    2. Cornflour 3kg min /li>
    3. Water
    4. Laminated cornfour picture

    Cornflour

    To make the stuff slowly add water to cornflour until it works - ask a committee member for help if you're getting stuck.

    Basically get them to have a play with the stuff, it's great to play with.

    Try and ask them whether it is a solid or a liquid (you may want to get them to come up with the terms solid and liquid first - eg what do we call hard things...)

    It is a solid and a liquid - solid when you move (more correctly, shear) it fast and liquid when you don't.

    Explanation

    This is a picture of cornflour under a confocal microscope (Bromley & Hopkinson) which takes a 2D slice through an image rather than looking at the surface. Cornflour is lots of irregular shaped particles that are seperated by water normally so are lubricated and can move. If you squash them together it will push the water sideways a little bit and let them touch - now they lock together and behave as a solid.

    It's like a room full of people and when you try and make it move quickly, everyone tries to move at once and they all get in each other's way and so no one can move anywhere. And when you do stuff to it slowly, everyone has time to move out of the way and file out.

    Thickening soups is different as then the cornflour grains open up when heated and release long starch molecules that tangle together forming a gel like substance.

    Industrial uses

    It is a problem in the oil industry, as when they are drilling they are getting rock fragments in the mud coming back up, if there are too many they behave similarly, with catastrophic results to pumps.

    Some people are talking about making liquid body armour using this effect, to make the body armour more comfortable.

    Toothpaste is an example of something that does the opposite to cornflour - when you shear it by squeezing it out of the tube, it flows, but when there's no shear, it sits quite happily on the toothbrush without flowing anywhere.

    Science background

    Corn flour is shear thickening. This means the higher rate of shear, the higher the viscosity (i.e. the thicker it is).

    The opposite of shear thickening is shear thinning. Many substances are shear thinning because the higher rate of shear can break up interparticular interactions and reduce the viscosity - e.g. shampoo.

    Thixotropy - a health warning

    Thixotropic / thixotropy is concerned with time related effects. The longer you shear a thixotropic fluid the lower the viscosity (the thinner it becomes) - e.g. paint - as you progressively break up interparticular interactions. Many fluids that are shear thinning are also thixotropic. However, this experiment has nothing to do with thixotropy. Thixotropy is a long word and shouldn't be used with children. Adults should be politely and gently explained the difference!

    Rheoplexy / Anti-thixotropy is the opposite - i.e. the longer you shear a fluid the higher the viscosity (the thicker it becomes). I think that xanthan gum might do this under certain conditions, but it's very rare for substances to do this.



     
     

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    Cornflour Risk Assessment

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  • Cornflour | 9 comments | Create New Account
    The following comments are owned by whomever posted them. This site is not responsible for what they say.
    Cornflour, Fluidised Bed and Thixotropic Sand
    Authored by: Dave on 04/12/03 @ 20:40 GMT
    apparently you can get graded sand from:
    http://www.pudlo.com/stanref.htm

    [ Reply to This ]

    Use for shear thickening fluids
    Authored by: Dave on 29/07/04 @ 13:07 BST
    I read this in Scientific American, and may be an interesting addition to the spiel

    "
    Individual soldiers, meanwhile, may get some added protection from a shear thickening fluid (STF) applied to fabrics like Kevlar. Hyped as "liquid armor" by some, the STF doesn't actually stop bullets but is very good at resisting stabs from knives and other sharp objects, according to ARL's Fink. "An ice pick easily penetrates Kevlar fabric," he says, "but I haven't yet met anyone strong enough to knock it through STF fabric."

    STF, which is made from polyethylene glycol, acts like a liquid until it comes into contact with a penetrating object like a knife. The STF then stiffens to a more rigid material that resists penetration. When applied to body armor, STF can reduce the thickness required for protection, thereby providing the wearer with more flexibility of movement. In addition to its use by soldiers, STF fabric may become a staple of prison guards and police officers. Fink thinks it could also be used for tires or products like ski boots given that STF fabric is initially flexible but stiffens under increased strain.
    "

    [ Reply to This ]

    Use for shear thickening fluids
    Authored by: rachel on 08/08/05 @ 13:25 BST
    I think they must be adding something to the PEG.

    [ Reply to This ]

    Use for shear thickening fluids
    Authored by: anthony on 09/08/05 @ 12:38 BST
    Don't think so, I don't think any additives are required at all. An appropriate amount of branching and molecular wieghts would be important factors.

    [ Reply to This ]

    Demonstrating in schools
    Authored by: Dave on 30/11/04 @ 15:52 GMT
    I demonstrated this in a school recently (to yr8s) I noticed that you had to put the cornflour at the end, as once they got their hands in it, htey were not interested in anything else!

    Probably less of an issue in CBS! as the experiemts will probably be split up, and the kids are smaller so you have less to get across

    [ Reply to This ]

    Thixotropic, Rheoplectic and More
    Authored by: rachel on 21/03/05 @ 13:48 GMT
    Corn flour is shear thickening. This means the higher rate of shear, the higher the viscosity (i.e. the thicker it is).

    The opposite of shear thickening is shear thinning. Many substances are shear thinning because the higher rate of shear can break up interparticular interactions and reduce the viscosity - e.g. shampoo

    Thixotropic / thixotropy is concerned with time related effects. The longer you shear a thixotropic fluid the lower the viscosity (the thinner it becomes) - e.g. paint - as you progressively break up interparticular interactions. Many fluids that are shear thinning are also thixotropic. However, this experiment has nothing to do with thixotropy. Thixotropy is a long word and shouldn't be used with children. Adults should be politely and gently explained the difference!

    Rheoplexy / Anti-thixotropy is the opposite - i.e. the longer you shear a fluid the higher the viscosity (the thicker it becomes). I think that xanthan gum might do this under certain conditions, but it's very rare for substances to do this.

    [ Reply to This ]

    Thixotropic, Rheoplectic and More
    Authored by: rachel on 21/03/05 @ 13:49 GMT
    Above bit about the experiment having nothing to do with thixotropy refers to cornflour part of experiment only.

    Thixotropic sand is, surprisingly, thixotropic.

    [ Reply to This ]

    Demonstrating in schools
    Authored by: rachel on 08/08/05 @ 13:28 BST
    The following analogy worked really well on the Roadshow this year. "It's like a room full of people and when you try and make it move quickly, everyone tries to move at once and they all get in each other's way and so no one can move anywhere. And when you do stuff to it slowly, everyone has time to move out of the way and file out."

    [ Reply to This ]

    Thixotropic Clays and the channel tunnel
    Authored by: Dave on 21/02/06 @ 12:17 GMT
    I was reading an article about the channel tunnel, apparently they pressurised the end of the boring machine with a Thixotropic clay, this meant that it would flow into the walls, and then solidify, and stabilise it, allowing you some time to put in the tunnel wall behind the cutting head.

    [ Reply to This ]